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6.

The following data were  obtained for a given reaction at 300K

 Reaction                             Energy of activation(kJ mol-1)

 (i) uncatalysed                             76

  (ii)  catalysed                              57

 the factor by which rate of catalysed reaction is increased , is 


A) 21

B) 2100

C) 2000

D) 1200



7.

A reaction: A2+B → products, involves the following mechanism

A22A  (fast)

  (a being the intermediate)

 A+B  k2  Products (slow)   The rate law consistent to this mechanism is 

         

 


A) rate=k[A2][B]

B) rate=k[A2]2[B]

C) rate=k[A2]1/2[B]

D) rate=k[A2][B]2



8.

In a reaction, A→ Products, when start is made from 80 x 10-2 M of A, the half-life is found to be 120 minutes. For the initial concentration  4.0 x 10-2 M  , the half-life of the reaction becomes 240 minutes. The order of the reaction is 


A) 0

B) 1

C) 2

D) 0.5



9.

 A plot In K against 1T (abscissa) is expected to be a straight line with intercept  on ordinate axis equal to 


A) S02.303R

B) S0R

C) -S0R

D) S0×R



10.

A moles of PCl5 is heated in a closed container to equilibrium   PCl5PCl3(g)+Cl2(g) at a pressure of p  atm. If x moles of PCl5 disscociate at equilibrium  , then

 


A) xa=KpKp+P

B) xa=(Kp+PKp)1/2

C) xa=(KpP)1/2

D) xa=(KpKp+P)1/2



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